First Officer: Riker or Kira. I prefer Kira as an individual character, but Riker and Picard have a good dynamic.
CMO: The Doctor
Helm: Sulu (Prime Universe)
Chief Engineer: O'Brien
Science Officer: Spock (Prime Universe)
Operations Officer: Data (Ops should be listed in the main selection)
Counselor: Troi. Ezri's hardly competition.
Bartenders: Quark & Guinan
Bad Guy: Dukat