Get music from Star Trek movies 1-11 as well as the Picard song. Seriously, while ALL the Trek scores are good, The Motion Picture and Wrath of Khan are particularly good with STO, while Star Trek IV... is not so much lol
any Star Trek Soundtrack will do, but ESPECIALLY...
Wrath of Kahn Soundtrack is amazing
Search for Spock Likewise
Aliens soundtrack (which is actualy Star Trek 4's original) also very nice
other good ones I enjoy... keep in mind this is all 'mood inspiring' and not 'rock n roll' stuff which im sure others can tell ya more about.
soundtrack from Perfect Storm (which is done by the guy who did all three trek's above)
soundtrack to Last of the Mohicans (i cannot stress enough how great that soundtrack is)
soundtrack to Bubba Hotep
that's what i use for serious contemplation or destroying starships